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Thermal ionization : ウィキペディア英語版
Thermal ionization

Thermal ionization, also known as surface ionization or contact ionization, is a physical process whereby the atoms are desorbed from a hot surface, and in the process are spontaneously ionized.
Thermal ionization is used to make simple ion sources, for mass spectrometry and for generating ion beams.
==Physics==

The likelihood of ionization is a function of the filament temperature, the work function of the filament substrate and the ionization energy of the element.
This is summarised in the Saha-Langmuir equation:
:\frac = \frac \exp \Bigg(\frac\Bigg)
where
::\frac = ratio of ion number density to neutral number density
::\frac = ratio of statistical weights (degeneracy) of ionic (g_+) and neutral (g_0) states
::e = electron charge
::W = work function of surface
::\Delta E_I = ionization energy of desorbed element
::k = Boltzmann's constant
::T = surface temperature
Negative ionization can also occur for elements with a large electron affinity \Delta E_A against a surface of low work function.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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